Wow. It took me a few days to get everything up and running working with so much data but in the end, it was all worth it. Thanks for all the help guys.
Time to install Emby or Plex on your NAS so you can serve your media anywhere! Not sure about Synology (I use QNAP), but I have mine set up to automatically download whatever shows I'm watching (using Usenet so pretty reliable, and extremely fast, and more importantly, not dependent on seeders, as in the case of torrents, and also more anonymous)
I use Sonarr to manage TV shows and Couchpotato for movies
Emby also lets me stream from my NAS to pretty much anywhere I am (or my friends are). Have friends who've cancelled their Netflix subscriptions in the US and just stream from my NAS here in manila
There's a lot your NAS can do, not just store media - good luck!